Preheat and Prep: Turn on the oven to 350°F (no fan) and prepare three 8-inch cake pans by lining them with parchment paper and buttering them well.
Dry Ingredients: In a bowl, mix flour, baking powder, baking soda, white sugar, brown sugar, and salt. Whisk until it’s smooth.
Wet Ingredients: In another bowl, beat eggs, vegetable oil, buttermilk, and sour cream until smooth.
Combine: Add the dry ingredients to the wet mixture in two batches. Stir gently each time, but don’t overmix.
Chocolate Mix: In a small bowl, combine cocoa powder and instant coffee. Pour boiling water over them, then whisk until smooth and shiny.
Finish Batter: Pour the chocolate mix into the main batter and fold it in until it’s rich and smooth.
Bake: Pour the batter evenly into the three cake pans. Bake for 22-24 minutes, until a toothpick comes out with just a few moist crumbs. Let the cakes cool in the pans for 20 minutes, then move to a wire rack to cool fully. (For best results, chill the cakes in the fridge for an hour.)